C/C坯体密度对反应熔渗制备C/C-SiC复合材料烧蚀性能的影响

    Influence of C/C density on the ablation performance of C/C-SiC composites prepared by reactive melt infiltration

    • 以2.5D无纬布/网胎叠层针刺预制体为增强体,制备了密度分别为(1.35±0.02 )、(1.50±0.02) g/cm3的两种C/C坯体,经反应熔渗制得C/C-SiC复合材料。在氧乙炔烧蚀与超声速富氧烧蚀环境下,研究了C/C坯体密度对针刺C/C-SiC材料微结构及烧蚀性能的影响,并分析了其烧蚀机理。结果表明:反应熔渗工艺制备的针刺C/C-SiC球头表面形成SiC富集层,内部形成连续SiC网络相,C/C坯体密度未改变SiC连续网络的整体结构特征,但低密度坯体制备的材料网络联通性更优、孔隙率更低、SiC含量更高。在氧乙炔烧蚀环境下,两种密度C/C坯体反应熔渗制备的C/C-SiC球头抗烧蚀性能相当,线烧蚀率为4.6×10−3~5.1×10−3 mm/s;而在超声速富氧烧蚀环境下,低密度C/C坯体熔渗制备的球头表现出更优异的抗烧蚀性能,线烧蚀率仅为3.1×10−3 mm/s。这主要归因于低密度坯体制备的C/C-SiC材料中SiC含量较高,可通过持续氧化生成充足的SiO2,对纤维形成有效防护,从而降低烧蚀率。

       

      Abstract: Using 2.5D fabric/mat layered needled preforms as reinforcements, two types of C/C preforms with densities of (1.35±0.02)g/cm3 and (1.50±0.02) g/cm3 were prepared, and then C/C-SiC composites were fabricated via reactive melt infiltration. Ablation tests were conducted on the prepared composites under oxyacetylene and supersonic oxygen-enriched ablation environments to investigate the effect of C/C preform density on the microstructure and ablation performance of needled C/C-SiC materials, and the ablation mechanism was analyzed. The results show that the surface of the needled C/C-SiC spherical head prepared by reactive melt infiltration forms a SiC-enriched layer, while a continuous SiC phase network forms inside; the C/C preform density does not change the overall structure of the SiC continuous network, but the material prepared from the low-density C/C preform exhibits better connectivity, lower porosity, and higher SiC content. The C/C-SiC spherical heads prepared from C/C preforms of different densities exhibit comparable ablation resistance under the oxyacetylene environment, with an ablation rate of 4.6×10−3~5.1×10−3 mm/s. However, under the supersonic oxygen-enriched ablation environment, the spherical head sample prepared from the low-density C/C preform shows better ablation resistance, with a linear ablation rate of 3.1×10−3 mm/s. This is mainly attributed to the higher SiC content in the C/C-SiC composites prepared from the low-density C/C preform, which can continuously oxidize to generate sufficient SiO2 to effectively protect the fibers, thereby reducing the ablation rate.

       

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